Blar i forfatter "Charboneau, David J."

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    • Ligand and solvent effects on CO2 insertion into group 10 metal alkyl bonds 

      Deziel, Anthony P.; Espinosa, Matthew; Pavlovic, Ljiljana; Charboneau, David J.; Hazari, Nilay; Hopmann, Kathrin Helen; Mercado, Brandon Q. (Journal article; Tidsskriftartikkel; Peer reviewed, 2022-02-09)
      The insertion of carbon dioxide into metal element σ-bonds is an important elementary step in many catalytic reactions for carbon dioxide valorization. Here, the insertion of carbon dioxide into a family of group 10 alkyl complexes of the type (<sup>R</sup>PBP)M(CH<sub>3</sub>) (<sup>R</sup>PBP = B(NCH<sub>2</sub>PR<sub>2</sub>)<sub>2</sub>C<sub>6</sub>H<sub>4</sub><sup>−</sup>; R = Cy or <sup>t</sup>Bu; ...